Villano V began working for World Championship Wrestling (WCW) in 1996. Villano V made his debut at the 1996 World War 3 event as part of the three ring, 60-man battle royal. Subsequently, he worked mainly the weekend shows such as WCW WorldWide and WCW Saturday Night. Villano V, as well as Villano IV, also worked an eight-man tag match at Clash of the Champions XXXV, alongside Psychosis and Silver King against Juventud Guerrera, Super Calo, Héctor Garza and Lizmark, Jr..
Villano V passed away on August 29, 2024.